Cis–Trans Interconversion in Ruthenium(II) Bipyridine Complexes

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Optically Induced Valence Tautomeric Interconversion in Cobalt Dioxolene Complexes

A descoberta de que vários complexos de cobalto-dioxoleno exibem bi-estabilidade magnética foto induzida foi descrita recentemente. Este fenômeno encontra-se sempre associado a processos de interconversão de tautômeros de valência entre espécies de cobalto(III) baixo spin e de cobalto(II) alto spin. Enfatiza-se, nesta revisão, a forte correlação formal existente entre estes processos e o efeito...

متن کامل

RutheniumII complexes bearing fused polycyclic ligands: from fundamental aspects to potential applications.

In this review, we first discuss the photophysics reported in the literature for mononuclear ruthenium complexes bearing ligands with extended aromaticity such as dipyrido[3,2-a:2',3'-c]phenazine (DPPZ), tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]-phenazine (TPPHZ),  tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]acridine (TPAC), 1,10-phenanthrolino[5,6-b]1,4,5,8,9,12-hexaazatriphenylene ...

متن کامل

RutheniumII(η6-arene) complexes of thiourea derivatives: synthesis, characterization and urease inhibition.

RuII(arene) complexes have emerged as a versatile class of compounds to design metallodrugs as potential treatment for a wide range of diseases including cancer and malaria. They feature modes of action that involve classic DNA binding like platinum anticancer drugs, may covalent binding to proteins, or multimodal biological activity. Herein, we report the synthesis and urease inhibition activi...

متن کامل

Synthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine

Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine;  (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...

متن کامل

Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes.

Seven bipyridine adducts of molybdenum imido alkylidene bispyrrolide complexes of the type Mo(NR)(CHCMe(2)R')(Pyr)(2)(bipy) (1a-1g; R = 2,6-i-Pr(2)C(6)H(3) (Ar), adamantyl (Ad), 2,6-Me(2)C(6)H(3) (Ar'), 2-i-PrC(6)H(4) (Ar(iPr)), 2-ClC(6)H(4) (Ar(Cl)), 2-t-BuC(6)H(4) (Ar(t) (Bu)), and 2-MesitylC(6)H(4) (Ar(M)), respectively; R' = Me, Ph) have been prepared using three different methods. Up to th...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Inorganic Chemistry

سال: 2019

ISSN: 0020-1669,1520-510X

DOI: 10.1021/acs.inorgchem.9b01485